Product ID:FYRQUEL 220 MLT
MSDS Date:12/08/1999
FSC:9150
NIIN:01-113-2046
MSDS Number: CGLTW

Emergency Phone: 914-693-6946 (MEDICAL)

Info Phone: 914-674-5000/800-666-1200

Preparer: NOT PROVIDED

Cage: 01GF0

Telephone: 504-366-9105

Cage: 0PGK2

TRIPHENYL PHOSPHATE

CAS: 115-86-6

RTECS: TC8400000

OSHA PEL 3 MG/M3

ACGIH TLV: 3 MG/M3

BUTYLATED TRIPHENYL PHOSPHATE (MIXTURE)

OSHA PEL NOT DETERMINED

ACGIH TLV: NOT DETERMINED

LD50 LC50 Mixture:LD50 (ORAL, RAT) IS >5,000 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION: INHALATION OF
VAPORS OR MISTS MAY CAUSE RESPIRATORY TRACT IRRITATION. TRIPHENYL
PHOSPHATE MAY CAUSE CHOLINESTERASE INHIBITION. SYMPTOMS MAY INCLUDE
HEADACHE, NAUSEA, SWEATING, NUMBN ESS, SALIVATION, MUSCLE
TWITCHING, TREMORS, INCOORDINATION, BLURRED VISION, TEARS,
ABDOMINAL CRAMPS, DIARRHEA, CHEST DISCOMFORT. SKIN CONTACT: MAY
CAUSE MILD IRRITATION. EYE CONTACT: MAY CAUSE MILD IR RITATION.
INGESTION: MAY CAUSE IRRITATION OF THE GASTROINTESTINAL SYSTEM AND
DIARRHEA. INGESTION OF TRIPHENYL PHOSPHATE MAY CAUSE CHOLINESTERASE
INHIBITION. CHRONIC: MAY CAUSE SKIN IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION OF VAPORS OR MISTS MAY CAUSE
RESPIRATORY TRACT IRRITATION, HEADACHE, NAUSEA, SWEATING, NUMBNESS,
SALIVATION, MUSCLE TWITCHING, TREMORS, INCOORDINATION, BLURRED
VISION, TEARS, ABDOMINAL CRAM PS, DIARRHEA, CHEST DISCOMFORT. SKIN
CONTACT MAY CAUSE MILD IRRITATION. EYE CONTACT MAY CAUSE MILD
IRRITATION. INGESTION MAY CAUSE IRRITATION OF THE GASTROINTESTINAL
SYSTEM AND DIARRHEA.
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING
NEUROMUSCULAR DISORDERS MAY HAVE INCREASED SUSCEPTIBILITY TO THE
TOXICITY OF EXCESSIVE EXPOSURES.

First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET
MEDICAL ATTENTION. SKIN CONTACT: REMOVE CONTAMINATED CLOTHING.
THROUGHLY WAS H AFFECTED AREA WITH SOAP AND PLENTY OF WATER . GET
MEDICAL ATTENTION IF IRRITATION PERSISTS. EYE CONTACT: IMMEDIATELY
FLUSH EYES WITH PLENTY OF RUNNING WATER. REMOVE CONTACT LENSES.
HOLD EYELIDS APAR T DURING FLUSHING. GET MEDICAL ATTENTION IF
IRRITATION PERSISTS. INGESTION: CALL A PHYSICIAN/POISON CONTROL
CENTER IMMEDIATELY. DO NOT INDUCE VOMITING UNLESS DIRECTED BY
MEDICAL PERSONNEL. IF VOMITING OCCURS, KEEP HEAD BELOW HIPS.

Flash Point Method:PMCC
Flash Point:=246.1C, 475.F
Autoignition Temp:Autoignition Temp Text:N/D
Lower Limits:N/D
Upper Limits:N/D
Extinguishing Media:USE WATER FOG OR SPRAY, DRY CHEMICAL, FOAM OR
CARBON DIOXIDE EXTINGUISHING AGENTS.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD WEAR FULL-FACE,
SELF-CONTAINED BREATHING APPARATUS AND IMPERVIOUS PROTECTIVE
CLOTHING. IF POSSIBLE, MOVE CONTAINERS FROM THE FIRE AREA. IF NOT
LEAKING, KEEP FIRE EXPOSED CONTAINER S COOL WITH WATER FOG OR
SPRAY. AVOID HIGH PRESSURE WATER. DIKE FIRE CONTROL WATER FOR
DISPOSAL.
Unusual Fire/Explosion Hazard:THIS PRODUCT IS NOT DEFINED AS FLAMMABLE
OR COMBUSTIBLE. IT IS SELF-EXTINGUISHING ONCE THE SOURCE OF
IGNITION IS REMOVED.

Spill Release Procedures:STOP SPILL AT SOURCE IF WITHOUT RISK. DIKE
AREA. SOAK UP LIQUID WITH A SUITABLE ABSORBENT SUCH AS CLAY,
SAWDUST/KITTY LITTER. SWEEP UP ABSORBENT MATERIAL AND PLACE IN A
CHEMICAL WASTE CONTAINER FOR DI SPOSAL. CAUTION: SPILL AREA MAY BE
SLIPPERY. COVER SPILL AREA WITH A SLURRY OF POWDERED HOUSEHOLD
DETERGENT AND WATER. USE STIFF BRUSH. WAIT 2-3 MINUTES, THEN FLUSH
WITH WATER. DO NOT FLUSH TO SEWERS.
Neutralizing Agent:NOT RELEVANT

Handling and Storage Precautions:STORE AWAY FROM FOODSTUFFS AND ANIMAL
FEED. CONTINERS SHOULD BE STORED IN A COOL, DRY, WELL-VENTILATED
AREA AWAY FROM FLAMMABLE OR OXIDIZING MATERIALS AND SOURCES OF HEAT
OR FLAME. PREVENT DAMAGE TO C ONTAINERS. AVOID PROLONGED STORAGE AT
ELEVATED TEMPERATURE UNDER WET ALKALINE OR ACIDIC CONDITIONS.
Other Precautions:AVOID EYE AND SKIN CONTACT. HANDLE IN WELL-VENTILATED
AREA. AVOID INHALATION OF VAPORS OR MIST. WASH THOROUGHLY AFTER
HANDLING. EMPTIED CONTAINER MAY RETAIN PRODUCT RESIDUES. FOLLOW ALL
WARNINGS AND P RECAUTIONS EVEN AFTER CONTAINER IS EMPTIED.

Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE
CONCENTRATIONS TO AN ACCEPTABLE LEVEL, A NIOSH-APPROVED ORGANIC
VAPOR/ ACID GAS RESPIRATOR WITH DUST, MIST AND FUME FILTERS MUST BE
WORN. FOR HIGHER LE VEL OF PROTECTION, USE ANIOSH-APPROVED,
POSITIVE-PRESSURE, PRESSURE DEMAND, AIR-SUPPLIED RESPIRATOR. CHANGE
CARTRIDGES OR CANISTERS FREQUENTLY.
Ventilation:WELL
Protective Gloves:NEOPRENE
Eye Protection:CHEMICAL SAFETY GOGGLES OR FACE SHIELD
Other Protective Equipment:SUITABLE PROTECTIVE CLOTHING, GLOVES, FOOT
WEAR
Work Hygienic Practices:NOT PROVIDED
Supplemental Safety and Health
ABBREVIATION: N/A=NOT APPLICABLE OR NOT AVAILABLE. N/K=UNKNOWN. N/P=NOT
PROVIDED. N/R=NOT RELEVANT. N/D=NOT DETERMINED. N/E=NOT
ESTABLISHED. CNS=CENTRAL NERVOUS SYSTEM. GI=GASTROINTESTINAL.

HCC:V6
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:NOT DETERMINED
Melt/Freeze Pt:M.P/F.P Text:NOT DETERMINED
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:< 0.1 @ 100F
Vapor Density:N/D
Spec Gravity:NOT DETERMINED
Viscosity:220 SUS @100F
Evaporation Rate & Reference:NOT DETERMINED
Solubility in Water:<0.1%
Appearance and Odor:CLEAR, BLUE LIQUID - ESSENTIALLY ODORLESS
Percent Volatiles by Volume:N/D
Corrosion Rate:NOT PROVIDED

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS, STRONG ALKALIS
Stability Condition to Avoid:ELEVATED TEMPERATURES (ABOVE 65.5 C/150F)
AND INCOMPATIBLES
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
OXIDES OF PHOSPHORUS, PHENOL, SUBSTITUTED PHENOLS, ARYL PHOSPHORIC
ACIDS MAY BE FORMED.

Waste Disposal Methods:MATERIAL THAT CANNOT BE USED OR CHEMICALLY
REPROCESSED SHOULD BE DISPOSED OF IN ACCORDANCE WITH ALL APPLICABLE
REGULATIONS. PRODUCT CONTAINERS DESIGNED FOR SINGLE USE SHOULD BE
THOROUGHLY EMPTIED BEF ORE DISPOSAL. NOTE: STATE AND LOCAL
REGULATIONS MAY BE MORE STRINGENT THAN FEDERAL.

Toxicological Information:ACUTE INHALATION LC50 (RAT) > 3.1 MG/L
(4-HOURS). DERMAL: PRACTICALLY NON-TOXIC. LD50 (RABBIT) > 2000
MG/KG. LD50 (ORAL, RAT) > 5,000 MG/KG. NEUROTOXICITY: NONE NOTED.
TARGET ORGANS: OVEREXPOSURE MAY AFFECT THE SKIN, EYES, RESPIRATORY
SYSTEM, AND CENTRAL AND PERIPHERAL NERVOUS SYSTEM.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:ECOTOXICOLOGICAL INFORMATION: 96-HR. LC50 (RAINBOW TROUT): >
2 MG/L. 96-HR. LC50 (SHEEPSHEAD MINNOW): > 1 MG/L. 96-HR. LC50
(MYSID SHRIMP): = 0.39 MG/L. TRIARYL PHOSPHATE ESTERS, INCLUDING
TRIPHENYL P HOSPHATE, EXHIBIT LOW AQUEOUS SOLUBILITY, HAVE MODERATE
POTENTIAL FOR BIOCONCENTRATION, AND READILY UNDERGO BIODEGRADATION.
HYDROLYSIS RATES OF TRIPHENYL PHOSPHATE ARE: AT PH 9.5: HALF-LIFE:
0.23 DAY. AT PH 8.2: HALF-LIFE: 7.5 DAYS.

Transport Information:NON-BULK (<= 119 GALLONS): NOT REGULATED. BULK
(>119 GALLONS) ARE REGULATED AS: ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, LIQUID, N.O.S. (TRIPHENYL PHOSPHATE 10-48%), 9, UN3082,
PG I I I. NORTH AMERICAN EM ERGENCY RESPONSE GUIDE NO. 171.

SARA Title III Information:NOT PROVIDED
Federal Regulatory Information:TSCA LISTED.
State Regulatory Information:MASSACHUSETS SUBSTANCE LIST; NEW JERSEY
RIGHT-TO-KNOW HAZARD. SUB.; PENNSYLVANIA HAZARDOUS SUBSTANCE LIST.